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ESTIMATE OZONE FROM FUEL REFORMULATION

Project No. A-67

Leaders:   R. S. MacArthur

                  A. M. Dunker

Scope and Objective

The objective of this project is to estimate ambient O3 changes due to the prospective use of biofuel blends. An emissions-processing scheme is to be developed which quickly applies on-road and nonroad emissions changes due to transportation fuel reformulation to result in a grid-model-ready emissions inventory.  A "companion" CAMx grid model O3 application (e.g., a SIP episode) will serve to predict the results from the emissions inventory changes, thus a "model suite."

Current Status and Future Program

Biofuel blends in transportation fuel are being required by many states--as well as by the federal renewable fuel standard (RFS)--consequently requiring regulatory decision-makers to demonstrate National Ambient Air Quality Standards (NAAQS) compliance with these measures in place.  There is concern since vehicle emissions tests have indicated some increase in permeation HC emissions due to ethanol, and some increase in NOx emissions from both biodiesel and ethanol.

Although generalizations about VOC- or NOx -limitation in the airshed may be helpful, mixed blends, the market penetration of the blends, and spatial and temporal variation of both mobile source HC and NOx increases render the predictability less certain.  Since "sound science" grid modeling applications of the simplest of control strategies are time consumptive and burdensome, and since the release timing of vehicle emissions testing results is highly uncertain, it seems prudent to develop a flexible modeling methodology which enables the timely grid modeling investigation of how the vehicle emissions testing results may be represented in the mobile source fleet and the consequent response of ambient ozone.

Through close coordination with Lake Michigan Air Directors Consortium (LADCO), the Consolidated Community Emissions Processing Tool (CONCEPT) will be modified to enable flexibility in changes in on-road (link-based) and nonroad temporal and spatial speciated- process- vehicle-specific ozone precursor emissions external from the grass-roots emissions development process.  The emissions inventory can then be used as input to CAMx to show the effects of fuel reformulation in the airshed.  The "model suite" is intended for decision-makers' and consultants' use to speed up delivery of results and reduce costs.  The project deliverables include a journal article, a model user's guide, public domain-resident code, models and model inputs.  CRC issued a request for proposal for this study, and a project start is anticipated later in 2007.

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